YBhg Tan Sri Dato' Seri Mohd Zuki bin Ali was appointed as a Member of Corporation (MOC) on 2 February 2022.

His career in the Public Service, particularly in Diplomatic Governance Service, began when he was appointed as Assistant Secretary at the Ministry of Finance Malaysia in December 1992. Over the last 30 years in Government service, his career has spanned across several ministries such as the Ministry of Education, the Ministry of Rural Development, the Ministry of Home Affairs and the Ministry of Natural Resources and Environment. He has held various positions of leadership during that time, such as Chief Assistant Secretary, Special Officer to the Minister and Senior Private Secretary to the Minister. From 2006 to 2011, his high leadership qualities were recognised when he was appointed as the Senior Private Secretary to His Majesty the Yang di-Pertuan Agong. 

YBhg Tan Sri Dato' Seri Mohd Zuki was then assigned to the Prime Minister's Department, where he held various positions such as Senior Consultant, Divisional Secretary, Deputy Chief Secretary (Management), Director General of Legal Affairs Division, Sarawak State Federal Secretary and finally as Senior Deputy Chief Secretary in 2017. He was appointed as Chief Secretary of the Ministry of Defense in 2019. YBhg Tan Sri Dato’ Seri Mohd Zuki was appointed as the 15th Chief Secretary to the State on 1 January 2020, and subsequently, a year later he was appointed as UKM Pro-Chancellor. He also chairs various Government-Linked Companies such as MRL Sdn Bhd, Cyberview Sdn Bhd, Sinergi Perdana Sdn Bhd, Razak School of Government and Malaysian Institute of Integrity.

He graduated with a Bachelor of Economics from Universiti Kebangsaan Malaysia and then obtained his Master of Business Administration (Finance) from Nanyang University, Singapore in a collaboration programme with the Massachusetts Institute of Technology, Boston. YBhg Tan Sri Dato’ Seri Mohd Zuki has received several awards in recognition of his contributions throughout his service. He was awarded the Excellent Service Award by the Ministry of Finance, the Ministry of Rural and Regional Development, as well as the State Palace. In addition, he was honoured with various medals including Darjah Indera Mahkota Pahang (Pahang State) in 2009, Panglima Setia DiRaja (Federal) in 2011, Seri Mahkota Wilayah (Federal) in 2018 and Darjah Panglima Mangku Negara which carries the title of Tan Sri for his loyalty and service to the King and country. In 2022, he was awarded the Terengganu State Level Maal Hijrah.